Aside from the other choices already mentioned (especially Doom stuff, FreeDoom ftw) any of the free games derived from the S.T.A.L.K.E.R. games and early builds, mostly Anomaly and Lost Alpha. There are also a few stabilized versions of the Build 1935 alpha out there which are worth playing and probably a bit more approachable for most people.
Aside from the other choices already mentioned (especially Doom stuff, FreeDoom ftw) any of the free games derived from the S.T.A.L.K.E.R. games and early builds, mostly Anomaly and Lost Alpha. There are also a few stabilized versions of the Build 1935 alpha out there which are worth playing and probably a bit more approachable for most people.